Self-assembled monolayers (SAMs) are an important element of modern nanotechnology. 1, 2 Among other applications, they can be used for the fabrication of monomolecular insulator films of well-defined thickness in the sub-nm to few nm range to provide an alternative to commonly used oxide dielectrics in future, nano-scale electronic and spintronic devices, and also in organic electronics.
Self-assembled monolayers (SAM) of organic molecules are molecular assemblies formed spontaneously on surfaces by adsorption and are organized into more or less large ordered domains. In some cases molecules that form the monolayer do not interact strongly with the substrate. This is the case for instance of the two-dimensional supramolecular networks of e.g. perylenetetracarboxylic.
View Self Assembled Monolayer Research Papers on Academia.edu for free.Characterisation of self-assembled monolayers? Can anyone suggest the best way to characterise a self-assembled monolayer (SAM), grown on a gold surface? Materials Chemistry.Keywords:SAMs, monolayer, characterization, SAM formation. Introduction Self assembled monolayers (SAMs) are highly ordered molecular assemblies formed spontaneously by chemisorptions and self organization of long chain molecules on the surface of appropriate substrates. This is an interesting process for its biological.
Self-Assembled Monolayers Self-assembled monolayers (SAMs) are ordered molecular assemblies formed by the adsorption of amphiphilic, surfactant-type molecules on solid surfaces. The substrate is generally immersed into a dilute solution of the film molecules or suitable precursors thereof and a monolayer film forms spontanously in a time span of a few minutes to a few hours.Read More
Self-Assembly: From Nature to The Lab. In the 1980’s, scientists discovered that alkanethiols spontaneously assembled on noble metals. This new area of science opened the doors to a simple way of creating surfaces of virtually any desired chemistry by placing a gold substrate into a millimolar solution of an alkanethiol in ethanol.Read More
Bhat et al. (2008) prepared Self-assembled monolayers (SAMs) of N-(3-diethylphosphatoxy)propyl-11-mercaptoundecanamide (PPMA) on gold surfaces. The SAMs, consisting originally of a phosphonate surface functionality, were subjected to step-by-step acidic hydrolysis to reveal two different functional groups: (a) a hydroxyl and (b) a carboxylic group.Read More
The Characterization of Self-Assembled Monolayers on Copper Surfaces by Low-Temperature Plasma Mass Spectrometry.. Low temperature plasma Mass spectroscopy Self-assembled monolayers. V.S., Fonder, G., Delhalle, J., Mekhalif, Z.: Self-assembled monolayer formation on vopper: a real time electrochemical impedance study. J. Phys.Read More
We designed and synthesized phenylboronic acid as a molecular recognitionmodel system for saccharide detection. The phenylboronic acid derivatives that haveboronic acid moiety are well known to interact with saccharides in aqueous solution; thus,they can be applied to a functional interface of saccharide sensing through the formation ofself-assembled monolayer (SAM).Read More
Lecture 3: Self-assembled Monolayers (SAMs) Self-Assembled Monolayers Figure. Number of published articles dealing with selfNumber of published articles dealing with self-assembled monolayers per year, according to searches in the Chemical Abstracts and Science Citation Index databases Self-assembly and Nanotechnology.Read More
CHARACTERIZATION OF SELF-ASSEMBLED MONOLAYERS FOR USE AS A MATRIX IN LASER DESORPTION IONIZATION. THESIS. Presented to the Graduate Council of. Texas State University-San Marcos. in Partial Fulfillment. of the Requirements. for the Degree. Master of SCIENCE. by. Kevin L. Francis, B.A. San Marcos, Texas. August 2007.Read More
This chapter discusses self-assembled monolayer on silicon. The chapter explains self-assembling, in which minute elements such as atoms, molecules, and clusters are spontaneously organized into.Read More
Refer to Manual for 2NANO2 “Kinetics of Au Colloid Monolayer Self-Assembly” pages 25-27. RESULTS AND DISCUSSION: It was not possible to obtain our own accurate results for this experiment because the solution that was prepared could not yield the anticipated results, as it was affected due to waiting as another group was using the UV spectroscopy.Read More
The aim of our work was to synthetize of a new analogue of abiraterone—thiolated abiraterone (HS-AB) and design a gold surface monolayer, bearing in mind recent advances in tuning monolayer structures and using them as efficient drug delivery systems. Therapeutic self-assembled monolayers (TSAMs) were prepared by chemically attaching HS-AB to gold surfaces.Read More